منابع مشابه
Nitrides: Transition Metal Solid-State Chemistry
Together with the transition metal carbides and borides, the transition metal nitrides belong to a family of materials that features an unusual combination of outstanding properties, among which are exceptional hardness, high melting point, metallic luster with sometimes vivid colors, and simple metallic structures combined with excellent electrical and thermal conductivities. This combination ...
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The definition of the continuous chirality measure(CCM) is provided and its applications are summarized in this tutorial review, with special emphasis on the field of transition metal complexes. The CCM approach, developed in recent years, provides a quantitative parameter that evaluates the degree of chirality of a given molecule. Many quantitative structural correlations with chirality have b...
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In this review we describe recent advances in transition metal oxyhydride chemistry obtained by topochemical routes, such as low temperature reduction with metal hydrides, or high-pressure solid-state reactions. Besides the crystal chemistry, magnetic and transport properties of the bulk powder and epitaxial thin film samples, the remarkable lability of the hydride anion is particularly highlig...
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The great diversity and richness of transition metal chemistry, such as the features of an open d-shell, opened a way to numerous areas of scientific research and technological applications. Depending on the nature of the metal and its environment, there are often several energetically accessible spin states, and the progress in accurate theoretical treatment of this complicated phenomenon is p...
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Dimers are the smallest chemical objects that show magnetic anisotropy. We focus on 3d and 4d transition metal dimers that have magnetic ground states in most cases. Some of these magnetic dimers have a considerable barrier against re-orientation of their magnetization, the so-called magnetic anisotropy energy, MAE. The height of this barrier is important for technological applications, as it d...
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ژورنال
عنوان ژورنال: Chemical Reviews
سال: 2000
ISSN: 0009-2665,1520-6890
DOI: 10.1021/cr980385s